瑞禧生物货号:Ruixi-B430400
化学名称:[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium
同义名称:(SP-4-2)-[(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]dichlororuthenium; [SP-4-2-(S)]-[[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]-P,P']dichlororuthenium; (S)-[1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine Ruthenium Complex; (S)-BINAP Dichlororuthenium Complex
CAS号:134524-84-8
分子式:C₄₄H₃₂Cl₂P₂Ru
Appearance:Dark Yellow to Dark Brown Solid
Melting Point:229-232ºC(dec.)
分子量:794.65
Storage:4°C, Inert atmosphere
Solubility:Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
Stability
Air Sensitive, Moisture Sensitive
产品类别:Building Blocks; Catalyst; Miscellaneous;
产品应用:[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.
参考文献:Li, Y., et al.: J. Chem. Res-S., no vol., 567 (2002); Makino, K., et al.: Tetrahedron-Asymmetr., 19, 2816 (2008)
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