瑞禧生物货号:Ruixi-B430370
化学名称:2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
同义名称:1,1'-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine];
CAS号:98327-87-8
分子式:C₄₄H₃₂P₂
Appearance:White to Off-White Solid
Melting Point:>200ºC (dec.)
分子量:622.67
Storage:20°C, Inert atmosphere
Solubility:Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),
产品类别:Building Blocks; Catalyst;
产品应用:2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene is a powerful chiral auxiliary that is used as a homogeneous catalyst in some asymmetric chemical syntheses. 2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene is utilized for its high enantioselectivity and is used as a ligand to create coordination complexes.
参考文献:DiBari, L., et al.: J. Am. Chem. Soc., 121, 7998 (1999); Hatano, M., et al.: J. Am. Chem. Soc., 130, 16858 (2008); Kitamura, M., et al.: Tetrahedron Lett., 32, 4163 (1991); Shimada, T., et al.: J. Org. Chem., 66, 8854 (2001)
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