瑞禧生物货号：Ruixi-B418013
化学名称：tert-Butyl N-(2-Bromo-6-fluorophenyl)carbamate
同义名称：N-​(2-​Bromo-​6-​fluorophenyl)carbamic Acid 1,​1-Dimethylethyl Ester; 1,1-Dimethylethyl N-(2-Bromo-6-fluorophenyl)carbamate; tert-Butyl (2-Bromo-6-fluorophenyl)carbamate
CAS号：1057720-25-8
分子式：C₁₁H₁₃BrFNO₂
分子量：290.13
产品类别：Building Blocks; Miscellaneous;
产品应用：tert-Butyl N-(2-Bromo-6-fluorophenyl)carbamate can be used in the preparation of indolines, isoquinolinones, and indoles by palladium-catalyzed annulation of substituted haloanilines or substituted halobenzamides with norbornadiene as an acetylene synthon. It can be useful in the preparation of ring-fluorinated N-Boc methyleneindolines via ortho lithiation and bromination of fluorinated anilines followed by nucleophilic addition of propargyl bromide and radical-induced ring closure. It can be useful in the synthesis of indoles via intramolecular 5-endo-dig carbocupration from N-aryl-ynamides.
参考文献：Thansandote, P., et al.: J. Org. Chem., 74, 1673 (2009); Bellezza, F., et al.: J. Fluorine Chem., 129, 97 (2008); Gati, W., et al.: Org. Lett., 15, 3122 (2013)
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